The web cam is such a great idea!
Yes, with time she will get used to being alone. Josie was 13 weeks old and I wasn't working at the time so, I got to be with home all the time. Now I ended up getting a F/T job so she's alone for 9 hours at a time. There times where I can go home and surprise her. My poor little girl she gets soo happy! So she will be okay, it's just so hard at the beginning. All will be fine.