I have a chi and a yorkie and I love the combo!! I wish I could have another of each.  Yorkies are very energetic, loving and they think they are big dogs while chihuahuas are a bit more timid but just as loving, a little more calm than yorkies but they are also very good watch dogs 

 .  They are both amazing breeds and I think you will really enjoy having  a chihuahua as a buddy to your yorkie.