Of course you can put pee pads together. I did this with four pads for Meg when I was trying to pad-train her. Just make sure the pads have plenty of overlap so you don't end up with the bottom of the pad (and floor) getting wet.
It's a good idea if you have a new puppy to cover his play area in pads, then slowly take them away until you are down to one. Good luck!
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