It isn't healthy for her to only have access to water twice a day.
It would be the same for humans.
If you were thirsty for hours and couldn't get something to drink, you'd be uncomfortable and begin to dehydrate.
It may be a fair compromise to put it out every hour and then take her out as soon as you think it has gone through but it really should be left out all the time. If she doesn't drink enough to process what she has eaten, etc., there could be issues later. Are you only feeding her twice a day?
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