How old is buddy?
There are a few different things that can cause itchy ears, so it is important to go to the vet for a diagnosis. It could be mites but it could also be a yeast infection, some other type of infection or allergies.
The OTC medicines may not be as safe or effective as prescription either.
As for getting him to sit still, have fun with that.
All you can do is restrain and hold his head against something (floor, leg, etc.) until you get the drops in and massage them down.
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